While Emile was going over the bios in the Hoenn Safari Zone, he encountered Pikachu. This encounter made him start the "Pikachu" Bio, when he threw a Safari Ball. Surprising to him, he caught Pikachu in one try.
- Rock Smash
- Thunder Wave
- Pikachu is the only Electric-Type Pokemon Emile captured in Pokémon Emerald.
- Pikachu can be seen in the Emerald PC Box in Pokémon Platinum - Episode 79: Park It while Emile is accessing in through Pal Park.